The above is known as a colour wheel and is the the simplest way to explain how colour interact with each other.
Primary colours of Blue, Yellow and Red are known as this because they cannot be 'made' by mixing another colour. By mixing two of these colours they create secondary colours like orange, green and purple. By mixing a primary with a secondary, this then produces tertiary colours like red-orange or blue-green.
Colours that sit next to each other on the colour wheel are referred to as harmonious because they share the same base colour. A good example like this are the colours yellow-orange, orange or red-orange because they share the same base colour of orange. Strong tones of this colour look sophisticated when pastel coloured tones create more of subtle effect.
Complimentary colours are ones that one the opposite side of the colour wheel. These when put together make a bolder statement creating a more dramatic effect. Each primary colour has a complementary secondary colour and visa versa. When the colours are mixed together they also have a neutralising effect on each other, which is the key in colour correcting like green neutralises any red areas on the skin.
When we talk about the different tones to the skin being cool or warm this is referring to the colour sets that will compliment this tone. The colours yellow-green to blue-violet are know as more cool as they lean towards the blue tones. The warmer tones are from yellow-orange to red-violet lean more towards to the red.
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